Group Presentations – Denmark Group

Catalytic Impurities in Organometallic Reactions	M. Albritton	08/13/2024
The Mysterious and Deadly Steroidal Alkaloid: BTX Two Stories in the History of Total Synthesis	R. Serrano	07/23/2024
Photo-enzymatic Synthesis : From Natural to Abiological Transformations	Y. Li	07/16/2024
Belzutifan: Evolution of a Sustainable Manufactuting Process	B. Ocampo	05/21/2024
Photochemical Palladium by Visible Light	J. Sura	04/16/2024
Strained Cyclic Allenes - Transient Intermediates with Expanding Synthetic Applications	C. Cunningham	02/27/2024
Taming Polar Organometallic Reagents: Resurgence of the Murahashi Coupling and Organometallic Reactions "On" Protic Solvents	N. Wade	02/20/2024
Contra-thermodynamic Alkene Isomerization vias Energy transfer(EnT)	D. Ouyang	01/30/2024
Electrochemically Mediated Photoredox Catalysis	M. Albritton	01/23/2024

Palladium (l) Dimers:	M.Bock	09/12/23
Atropisomerism: A Pharmaceutical and Process Perspective	B. Ocampo	10/31/23
Borrowing Hydrogen in Asymmetric Catalysis	C. Olen	09/26/23
Catalytic Enantioselective Ugi and Passerini Multicomponent Reactions	M. Albritton	05/16/23
CatellaniReaction: Mechanistic Investigations and Structurally Modified Norbornene Co-Catalysts	N. Wade	04/25/23
Group Transfer Polymerization (GTP)	D. Ouyang	04/18/23
An Introduction to Mechanochemistry: Underlying Theory and Applications in Organic Synthesis	C. Cunningham	03/21/23
Radioiodination and Its Uses in Radiomedicine	J. Berry	2/28/23
Lewis Base-Boryl Radical Enabled Reactions	B. Ocampo	2/21/23
Statistical Design of Experiments	T. Menard	1/24/23
Total Synthesis of Securinega Alkaloids	C. Olen	1/31/23

Daphniphyllum Alkaloids	M. Bock	11/29/22
Isocyanides: Anionic Methods for Dearomatizations to Complex Cyclohexadienes	B. Altundas	10/25/22
Enantioselective, Lewis Base-Catalyzed, Functionalization of Alkenes	J. Panger	7/19/22
Low Valent Group 4 Metal Complexes of Alkenes and Alkynes in Synthesis	A. Shved	6/21/22
Homogenous Au(I)/Au(III) Catalysis and Rationalizing Their Reactivity	B. Ocampo	5/24/22
Structural Revision of Natural Products	A. Feng	05/10/22
Development of a Commercial Process for Odalasvir	M. Albritton	3/29/22
Proton Coupled Electron Transfer (PCET): Physical Organic Analysis and Applications	J. Berry	3/22/22
Photoswitchable Catalysis	C. Olen	2/15/22
Gefapixant Citrate: A Merck Process GreenSynthesis Case Study	T. Menard	1/25/22
Practical Applications of Molecular Orbital Theory in OrganotransitionMetal Chemistry	N. Rinehart	1/18/22

Recent Advances in Biocatalytic Cascades	M. Bock	11/23/21
Industrial Photochemistry	E. Mumford	11/16/21
Carbon-Carbon Bond Functionalization Enabled by Transition-Metal Catalysts	V. Kassel	10/26/21
Cross Electrophile Coupling: Mechanistic Insights and Synthetic Application	J. Panger	09/28/21
Energy Decomposition Analysis	A. Shved	09/21/21
Reductive Epoxide Openings with Low- Valent Ti Reagents	B. Ocampo	5/25/21
Macrocyclization Strategies in Natural Product Total Synthesis	C. Olen	6/29/21
Silylium Ions	T. Menard	6/22/21
Retrosynthetic Analysis: How we think about synthesizing molecules	N. Rinehart	5/25/21
Recent Highlights in Total Syntheses of Prenylated Indole Alkaloids	E. Mumford	5/18/21
Strategies for the Total Syntheses of Dimeric Natural Products	J. Panger	4/27/21
Carbonyl-Olefin Metathesis	V. Kassel	4/20/21
Bilobalide	B. Rose	3/30/21
Cascade Pericyclic Reactions In Total Synthesis	K. Hilby	3/23/21
The Boronic Acid Mannich Reaction	B. Ocampo	2/16/21
Non-Cycloaddition Chemistry of Nitrones: Synthesis and Transformations	A. Kwong	1/26/21
The Life Work of Dietmar Seyferth	N. Rinehart	1/19/21

Life and Scientific Contributions of Hans Reich	J. Panger	10/28/20
An Exploration of Oxetanes: Synthesis and Relevance	K. Hilby	7/21/20
Catalytic, Enantioselective, Transfer Hydrogenation	T. Menard	6/20/20
The Catalytic, Enantioselective Favorskii Reaction: In Situ Formation of Metal Alkynylides and Their Additions to Aldehydes	A. Kwong	5/26/20
Organocatalysis in Multicatalytic Strategies	A. Matviitsuk	5/22/20
Catalytic Enantioselective Copper-Boryl Additions to Alkenes	C. Olen	5/19/20
Generation and Trapping of Functionalized Aryl and Heteroarylmagnesium and Zinc Compounds	I. Rinehart	4/29/20
Hydrofunctionalization of Alkenes by Hydrogen-Atom Transfer	J. Panger	4/21/20
Enantioselective Lithiation-Substitution of Nitrogen-Containing Heterocycles	E. Mumford	2/25/20
Carbon-Carbon Bond Formation by Metallophotoredox Catalysis	V. Kassel	1/28/20
The Negishi Cross-Coupling Reaction	W. Darrow	1/14/20

Cyclophanes: A Strained Overview	B. Rose	11/26/19
History of [1.1.1] Propellanes And Bicyclo [1.1.1] Pentanes	K. Hilby	10/29/19
Modern Synthesis of Illicium Natural Products	A. Roth	10/22/19
Studies Toward the Total Synthesis of Daphnicyclidin A	S. Bawel	9/17/19
Arynes: History, Reactivity, and Total Syntheses	T. Menard	8/13/19
Copper-Catalyzed Amino Oxygenation of Alkenes and Dienes: An Amino-Initiation Pathway Using O-Benzoylhydroxylamines	B. Hemric	7/30/19
Photoredoxpromoted fluoroalkylationof nitrones	I. Dmitriev	7/23/19
Electron Transfer-Mediated Substitution: SRN1 Reaction Discovery, Elucidation, and Legacy	I. Rinehart	7/16/19
Artemisinin	E. Mumford	6/25/19
History & Chemistry of High Energy Materials	J. Panger	6/18/19
Methods for Asymmetric Monofluorination	V. Kassel	5/21/19
Selected Recent Applications of Low-Talent Titanium Chemistry	B. Darrow	4/23/19
The Mechanistic Story of the Morita-Baylis-Hillman Reaction	B. Rose	4/17/19
The Bis-Indole Vinca Alkaloids	K. Hilby	4/9/19
Shikimic Acid – A Synthetic Star	T. Menard	3/12/19
Highlights of Leo Paquette’s Career: Breakthroughs in Total Synthesis	C. Parnell	2/26/19
Autonomous Optimization of Chemical Reaction in Flow	A. Zahrt	2/12/19
Catalytic Functionalization of Organoaluminum Reagents and Olefins by Cross-Coupling with Sustainable Metals	B. Shrestha	1/15/19

The Halogen Bond: Theory and Applications	C. Delaney	12/11/18
Five Years in the Denmark Lab	K. Robb	10/16/18
En Route to the Enantioselective syn-Dichlorination of Olefins	B. Gilbert	9/25/18
α,β-Unsaturated Acyl Ammonium Catalysis	A. Matviitsuk	8/28/18
Presentation–previous research	T. Qin	8/21/18
Stereodivergent Catalysis	A. Laverny	7/31/18
Transition Metal Hydrides: More Than You Wanted To Know	I. Rinehart	6/26/18
Self-Disproportion of Enantiomers (SDE)	J. Panger	6/19/18
Z-Selective Olefin Metathesis	E. Mumford	6/12/18
Chain-Walking Processes to Effect Remote Functionalization	V. Kassel	5/29/18
Stereogenic-Only-at-Metal Asymmetric Catalysis	B. Darrow	4/17/18
Functional Molecular Flasks	B. Rose	3/27/18
History of Pleuromutilin	K. Hilby	3/20/18
The Magic Methyl Effects	A. Roth	2/27/18
Molecular Motors, from Novelty to Function	S. Athavale	2/20/18
Computer-Assisted Retrosynthetic Planning	A. Zahrt	1/30/18
BMS-663068 A Process Chemistry Story	K. Robb	1/23/18

Industrial Organic Chemistry	M. Ibrahim	12/12/17
The Pauson-Khand Reaction	C. Delaney	10/24/17
Deprotonative metalation for the preparation of diversely-functionalized organometallic reagents	B. Gilbert	9/26/17
Resolving the Strategies for De-racemization	B. Rose	8/22/17
Bergman Cyclization and Enediyne Antibiotics	S. Athavale	6/20/17
Dispersion – Reconsidering Steric Interactions	A. Zahrt	6/13/17
Carbon-Carbon Bond Formation Driven by the Water-Gas Shift Reaction	Z. Matesich	3/28/17
Organic Molecules, Photoredox, and Catalysis	B. Rose	2/28/17
Singlet Oxygen	L. Calvo Parra	2/21/17
Cieplak Effect: Fact or Fiction?	K. Hilby	1/31/17
Flow Chemistry Applications in Organic Synthesis	M. Ibrahim	1/24/17
Pd-Catalyzed Asymmetric Allylation Reactions Using Olefins and Allylic Alcohols as Allylating Substrates	Z. Tao	1/17/17

The Tishchenko Reaction: Recent Advances, Modifications and Applications	K. Robb	11/29/16
The Willgerodt Reaction	B. Gilbert	11/15/16
Five Years in the Denmark Group	A. Ambrosi	7/19/16
Frondosin B: A Stereochemical Mystery	A. Roth	6/28/16
Artificial Metalloenzymes: A Catalysis Upgrade?	S. Athavale	5/17/16
The Maillard Reaction: Radicals and Flavor	N. Marcus	3/22/16
Masayuki Inoue and Total Synthesis of (+)-Ryanodin	K. Zhao	3/15/16
The Activation Strain Model	A. Zahrt	2/23/16
Enantioselective Benzoin Reactions	G. Zhang	2/16/16
Metallic Supported Nanoparticles as Catalysts	M. Ibrahim	1/26/16
Benzoxaboroles	R. Leising	1/19/16

Frustrated Lewis Pairs: Structure and Synthetic Applications	Z. Matesich	11/17/15
Vinigtol: A 25-year adventure	K. Robb	10/27/15
Sulfines: Tear-inducing reactive intermediates	B. Gilbert	09/29/15
Construction of Vicinal Quaternary Stereogenic Centers in One Step	N. Carson	09/22/15
Classics in T. Fukuyama’s Total Synthesis (post 2011)	K. Zhao	09/15/15
Highlights from OMCOS 18	A. Ambrosi	07/28/15
Cubanes: A symphony of high-energy intermediates	J. Henle	06/30/15
Building Architectures with DNA	S. Athavale	06/9/15
Ether C-O Bond Cleavage via Transition Metal Homogeneous Catalysis	R. Leising	05/12/15
The alpha effect	A. Zahrt	04/28/15
The Staunton-Weinreb Annulation	G. Zhang	04/21/15
Synergistic Catalysis	K. Robb	03/31/15
Sweet Molecules and the Molecular Theory of Taste	B. Gilbert	03/24/15
Aromaticity by Any Other Name	J. Henle	03/17/15
N-Heterocyclic Carbenes: Structure and Properties	Z. Matesich	02/24/15
High-throughput Experimentation: Designed Serendipity	A. Thomas	02/10/15

The Thorpe-Ingold effect	A. Ambrosi	11/18/14
Development of Novel Small Molecule Inhibitors of Neurotropic Alphaviruses	S. Barraza	10/28/14
De Novo Synthesis of Substituted Pyridines	D. Kornfilt	07/15/14
Aconitine-Type Alkaloids: C19- and C-18- norditerpenoid alkaloids	L. Cullen	06/24/14
Amphoteric Molecules	H. M. Chi	06/17/14
Cyclazines	N. Carson	05/27/14
Helicenes: Synthesis and Applications	K. Robb	05/20/14
Enolate Additions to Alkynes: The Nakamura Reaction	B. Gilbert	04/29/14
The Synthesis of P-Stereogenic Phosphorus Compounds: Increasing Accessibility to a Privileged Class of Ligand	C. Seymour	04/22/14
Photocatalysis: Formations of Rings	Z. Matesich	04/15/14
The Isoinversion Principle	A. Ambrosi	02/18/14
Palladium Catalyzed Dearomatization Reaction & Electrophilic Rearrangement of Amides	B. Peng	02/11/14
Steric Control of Stereoselectivities in a- and ß-Alkylation of Azulenone Intermediates in a Guanacastepene A Synthesis	H. Wang	01/28/14

The Beckmann Rearrangement: The Mona Lisa of Rearrangements	J. Henle	11/19/13
Transition Metal Catalyzed Hydroaminations of Alkenes	A. Thomas	10/29/13
Povarov Reaction	Z. Yousaf	10/22/13
Strained Alkenes in Natural Product Synthesis	H. M. Chi	10/15/13
Vitamins: From Theory to Industrial Synthesis in 100 Years	L. Cullen	09/24/13
National Organic Symposium 2013	D. Kornfilt	09/17/13
Total Synthesis of the Potent Antibiotic Platensimycin	S. Eey	09/10/13
The Asymmetric Baeyer-Villiger Oxidation	C. Seymour	07/16/13
Organic Electrochemistry	Z. Matesich	06/18/13
Chemical Space: Space, Diversity, and Synthesis	J. Henle	04/23/13
Chemistry of Ynamides	A. Thomas	03/19/13
Chiral Organolithium Reagents: Configurational Stability and Dynamic Resolution	A. Ambrosi	03/12/13
Ketyl Radical Anion in Samarium Iodide (SmI2) Chemistry: The “Kagan Reagent”	H. M. Chi	02/12/13
Rhodium-Catalyzed Asymmetric Conjugate Silyl Transfer: Stereoselective Access to the C7-C16 Fragment of (+)-Neopeltolide and Synthesis of Stereodefined Polyols	E. Hartmann	01/29/13

Understanding LDA Reactions through Kinetics & NMR Analysis	L. Cullen	11/27/12
Catalytic Intermolecular Hydroacylation in the Absence of Substrate Chelation Assistance	W. Kuester	11/13/12
2D-NMR Techniques for the Research Organic Chemist	A. Thomas	10/30/12
Development of Ion-Pair Cooperative Asymmetric Catalyses of Chiral Tetraaminophosphonium Salts Possessing Functional Organic Anions	Y. Ueki	10/23/12
Iridium-Catalyzed Allylic Substitution: A Mechanistic Study	Z. Matesich	10/16/12
Asymmetric Aziridination of Alkenes	D. Kornfilt	09/18/12
Sp3-sp3: The Final Challenge in Cross-Coupling	S. Eggen	08/28/12
Carbon Isotopes: Practical Applications in Organic Chemistry	A. Ambrosi	07/24/12
Recent Investigations of Enamine Catalysis with Prolinol Silyl Ethers	J. Henle	07/17/12
Arynes and Cyclohexynes	H. M. Chi	06/19/12
Organocatalytic C-H Activation or Homolytic Aromatic Substitution: A Cautionary Tale	W. Kuester	05/29/12
Organohypervalent Iodine: Application as a Hypernucleofuge	L. Cullen	05/22/12
Three Carbons, Two Electrons, One Ring: Recent Chemistry of Cyclopropenium Ions	D. Kornfilt	04/24/12
Anion Relay Chemistry	Z. Matesich	04/17/12
Investigations of Organocuprates	A. Thomas	03/20/12
Development and Applications of the Intramolecular Schmidt Reaction	S. Eggen	02/21/12
Total Synthesis of epi-Dictyostatins	A. Ambrosi	01/31/12
Chiral Ionic Liquids: An Adolescent Technology	J. Henle	01/24/12

Bimolecular Coupling Reactions Involving Single Electron Oxidations: Method Development and Mechanistic Studies	B. Casey	11/29/11
Oxidative Dearomatization of Phenols	H. M. Chi	08/23/11
Chiral Lewis Bases Activation of Trichlorosilyl Derivatives	S. Rossi	08/16/11
Aza-Wacker-Type Cyclization	W. Kuester	04/19/11
Nucleophilic and Electrophilic Trifluoromethylation	L. Cullen	03/29/11
Calcium Compounds in Catalysis	D. Kornfilt	03/15/11
π-π Interactions: Origin and Modulation	L. Wolf	01/18/11

Antiaromaticity	M. Burk	11/30/10
Recent Advances of Alkyne Metathesis	T. Chang	11/09/10
Pd Catalyzed Functionalization of Non-Acidic C(sp3)-H Bonds	L. Cullen	10/26/10
The Asymmetric Synthesis of Vitamin B12	N. Werner	09/28/10
Enantioselective Borylations	D. Kornfilt	09/14/10
Direct and Facile Metalation of Functionalized Substrates	R. Weintraub	08/17/10
Carbonyl Ylide Cycloadditions	N. Anderson	07/13/10
1,3-Dipolar Cycloadditions: FMO and Beyond	L. Wolf	06/15/10
Dyotropic Rearrangements	M. Burk	05/11/10
Transition Metal-Catalyzed 1,2-Diamination of Alkenes	T. Chang	04/27/10
Rhodium-Catalyzed C-H Amination	N. Werner	03/30/10
Phosphine Catalyzed? Addition to Activated Alkynes and Allenes	L. Cullen	03/23/10
Syntheses of the Kinamycin Family: Insights into Natural diazo Containing benzo[b]fluorenes	D. Kornfilt	03/16/10
Dynamic Chirality: A Novel Approach to Enantioselective Synthesis	N. Anderson	02/16/10
Continuous Chromatography: Simulated Moving Bed Systems and Operation	R. Weintraub	01/19/10

Reactivity within Confined Nano-spaces	L. Wolf	10/27/09
Parallel Kinetic Resolution	T. Chang	09/29/09
Nucleophilic Heterocyclic Carbene Catalysis	N. Werner	09/22/09
Synthesis and Conformational Analysis of Stevastelin C3 Analogs as Phosphatase Inhibitors	N. Bisek	09/08/09
Highlights from 2009 GRC- Heterocyclic Compounds	R. Smith	07/28/09
Asymmetric Fluorination	R. Weintraub	06/02/09
Site-Selectivity in Pd-Catalyzed Oxidative Functionalization Reactions	D. Kalyani	05/19/09
Non-Linear Effects in Asymmetric Catalysis: A Useful Tool in Understanding Reaction Mechanisms	A. Bailey	05/12/09
Vinblastine: A Total Synthesis Challenge	N. Anderson	04/28/09
Dynamics Considerations and Bifurcating Potential Surfaces	L. Wolf	04/21/09
Synthesis of Oxetanes: Paterno-Büchi Reaction and Cyclization Approach	T. Chang	04/14/09
Iron Catalyzed Cross Coupling: Mechanism and Application	M. Burk	03/10/09
Acid-Catalyzed Rapid Nazarov Cyclization and its Asymmetric Conversion	K. Yaji	02/17/09
Singly Occupied Molecular Orbital Organocatalysis	N. Werner	02/10/09
Mechanisms, Stereochemistry and Applications of Homogeneous Ziegler-Natta Polymerization	T. Wilson	01/27/09

Recent Advances in Quantifying Chirality	N. Duncan-Gould	12/09/08
Cortistatin A: A Strange Feeling of déjà vu	R. Smith	11/25/08
Atropisomeric 8, 8′-Biquinolyl Derivatives: Synthesis, Properties, and Applications	S. Milicevic	11/18/08
Synthesis of 9,11-Secosterols Intermediates and more	R. Aav	11/18/08
Ladderanes: Uses and Synthesis	N. Anderson	10/28/08
Studies on Heck and Suzuki Reactions Catalyzed by Palladium (0) and Wacker Type Oxidative Cyclization Catalyzed by Palladium (II)	Z. Zhang	10/21/08
Total Synthesis of Callipeltoside A	A. Bailey	09/23/08
Frustrated Lewis Pairs: Novel Reactivity and Mechanism	M. Burk	08/12/08
Gold Activation of pi-Systems [Propargylic Esters] What Makes Gold Special Relativity Speaking	L. Wolf	07/29/08
The Mechanism of Rhenium Catalyzed Olefination of Aldehydes	N. Werner	07/22/08
Enantioselective Protonation	T. Chang	07/08/08
Biology as a Tool for Synthetic Chemistry	N. Duncan-Gould	06/24/08
Combinatorial Approaches in Homogeneous Catalysis Development: Case Studies	M. Xie	06/17/08
Catalytic Carbonylative Ring Expansion of Epoxides and Aziridines	A. Hoover	06/10/08
Go With the Flow. . . Microfluidics and Microreactors: An Organic Chemist’s New Round Bottomed Flask	R. Smith	05/13/08
Pyrrole-Imidazole Alkaloids	T. Wilson	04/29/08
Alois Fürstner: Applying Organometallic Chemistry in Total Synthesis	C. Regens	04/22/08
Theory and Design of Mobius Molecules	W. Collins	04/08/08
The 5 W’s of Chiral Dienes as Ligands for Asymmetric Catalysis	C. Butler	03/25/08
Rhodium Catalyzed [5+2] Cycloaddition	A. Bailey	03/11/08
Nickel Catalyzed sp3-sp3 Couplings	N. Anderson	02/12/08
Interrupted Nazarov Cyclizations	M. Burk	01/29/08
The Petasis-Ferrier Union/Rearrangement	L. Wolf	01/22/08
Transition Metal-Catalyzed Carbon-Carbon Bond Cleavage (C-C Activation)	T. Chang	01/15/08

Total Synthesis of Azadirachtin: 22 Years to Harvest	N. Werner	12/11/07
The Mechanistic Studies of the Wacker Oxidation	T. Wilson	11/27/07
Methodologies for Synthesis of Cyclotryptamine Alkaloids	M. Xie	11/20/07
A Long-standing Argument Over the Transfer of a Hydride: Inner versus Outer Sphere Mechanisms Involving Imines	R. Smith	10/16/07
Recent Advances in the Chemistry of Allenamides	N. Duncan-Gould	09/25/07
Development of Alkenyldiarylmethanes (ADAMs) as Potential HIV/AIDS Therapeutics	M. Cullen	09/18/07
Tohru Fukuyama: Inspiring Nature Through Total Synthesis	C. Regens	09/11/07
Predicative Design of Stereoinduction in Catalytic, Asymmetric Reactions	W. Collins	08/28/07
Development of Chiral Phosphine–Olefin Ligands and Their Use in Asymmetric Catalysis	W-l. Duan	07/31/07
Synthetic Molecular Motors	W.-j. Chung	06/19/07
Asymmetric Total Synthesis of (+)-Nominine: Development of a Dual Cycloaddition Strategy for the synthesis of the Hetisine Alkaloids	K. Peese	05/15/07
From Biogenetic Isoprene Rule to Biomimetic Polyene Cyclization	J. Liu	05/08/07
Hypervalence and the Search for Pentavalent Carbon	M. Burk	04/17/07
The aza-Baylis-Hillman Reaction: Mechanism, Asymmetric Catalysis, & Abnormal Adducts	L. Wolf	04/10/07
Strategies and Synthesis of Contrathermodynamic Spiroketals	T. Chang	03/27/07
Application of Planar Chiral Heterocycles in Asymmetric Synthesis	N. Werner	03/20/07
Comparative Synthesis of Ingenol	T. Wilson	02/27/07
A Survey of Recent Advances in Non-Lewis Acid Catalyzed Catalytic, Enantioselective Cycloadditions	N. Duncan-Gould	02/20/07
Mechanistic Studies on Palladium-Catalyzed Aerobic Oxidations	P. Yao	01/30/07
Design and Development of Bioactive Compounds: Targeting HIV Protease, Neuronal PDZ, and Anticancer Analogs of Heterolignans	J. Muhuhi	01/23/07

Progress in the Synthesis of Guanacatepenes	C. Regens	12/12/06
Pt(II) Catalyzed Reorganization of Enynes: What Can You Do With a Platinum Carbene Intermediate	R. Smith	11/28/06
C-C Bond Formation through Catalytic Functionalization of sp3 C-H Bonds	M. Xie	10/17/06
Chelation-Based Stablization in the Transition-State Structure: Development of Hemilabile Ligand	W. Collins	09/12/06
Synthesis of the ABCD and FGHI Domains of Azaspiracid	S. Nguyen	08/22/06
Efficient Synthesis of Amines: From Reductive Amination of Aldehydes to Hydroaminomethylation of Olefins	M. Ahmad	08/08/06
Mechanistic Studies of Proline-Catalyzed Reactions	J. Liu	07/25/06
Quasienantiomers – Mutants of Enantiomers	W.-j. Chung	07/18/06
Asymmetric Bronsted Acid Catalysis	C. Butler	06/13/06
The Mechanism of Pd-Catalyzed Amination. Controversy? And Conclusion?	S. Tymonko	05/09/06
Recent Advances in Directed and Intramolecular Transition Metal Catalyzed Oxidative Functionalizations of Carbon-Hydrogen Bonds	J. Heemstra	04/18/06
Total Synthesis of Saxitoxin	J. Baird	04/11/06
Approaches Towards and Synthesis of Garsubellin A	J. Kallemeyn	02/28/06
Total Syntheses of Manzamine A.	R. Baiazitov	02/21/06
Synthesis of Morphine Alkaloids	T. Wilson	01/31/06
Transmetalation from Tin to Palladium in the Stille Reaction	P. Yao	01/24/06

The Exegesis of Olefin Metathesis: The Critical Mechanistic Experiments Leading to the [Almost] Complete Understanding of Olefin Metathesis	C. Butler	12/14/05
Reaction of Alkynes with Amino Chromium Fischer Carbene Complexes and Synthesis of N-Heterocycles	M. Xie	11/29/05
Self-Reproduction of Chirality: Development and Application of Butane 2,3-Diacetals	W. Collins	11/08/05
Wolfgang Oppolzer	C. Regens	10/18/05
Two or Three Things I Know About Group 8 Metals	S. Ito	09/20/05
Organometallic Approach to the Taxane Skeleton Involving New Iron Tricarbonyl Complexes	C. Eggertswyler	09/13/05
High Pressure Organic Reactions	J. Montgomery	08/30/05
Total Synthesis of the CP-molecules (Phomoirides A & B)	N. Duncan-Gould	08/23/05
Synthetic Developments Towards the Preparation of Erythromycin and Erythronolide Derivatives)	R. Smith	08/09/05
Enantioselective Vinylation of Aldehydes and Ketones	W. Chung	08/02/05
Total Synthesis of Stephacidin A, Avrainvillamide and Stephacidin B	J. Liu	07/26/05
Platinum-Catalyzed Skeletal Rearrangements of Enynes: a New Route to Cyclopropane Derivatives	T. Bui	07/19/05
Rearrangement of Oxonium and Ammonium Ylides	S. Tymonko	06/28/05
Synthetic Strategies Toward the Synthesis of Tetracyclines	J. Heemstra	06/21/05
Synthetic Approaches to Quinine	J. Baird	06/07/05
Zirconium Catalyzed Carboalumination of Alkynes: Mechanisms and Applications	N. Duncan-Gould	05/31/05
Rhodium Catalyzed Alkyl C-H Insertion Reactions	J. Kallemeyn	05/17/05
Toward the Total Synthesis of (+)-Gigantecin	B. Eklov	04/26/05
N—heterocyclic compounds via Radical Cyclization Reactions: Chemistry of the Imidoyl Radical	T. Wilson	04/12/05
Chiral N-Heterocyclic Carbene Ligands in Asymmetric Catalysis	P. Yao	03/22/05
Halogen-Metal Exchange	R. Baiazitov	03/08/05
Sulfur Ylides: Development of Enantioselective and Diastereoselective Epoxidation and Aziridination Reactions	R. Smith	02/15/05
Late Transition Metal Catalyzed Intermolecular Hydroamination of Alkenes	M. Xie	02/08/05
Rhodium Catalyzed C-C bond Forming Hydrogenation	M. Jo Patten	01/25/05
1,2-Metallate Rearrangement	C. Regens	01/18/05

Studies on the Total Synthesis of (-)-Apoptolidin	X. Liu	11/30/04
Asymmetric Transformations with Chiral Phase Transfer Catalyst	W. Chung	11/16/04
Chiral Bronsted Acid Catalysis	J. Liu	11/16/04
Ecteinascidin 743	C. R. Butler	10/26/04
Chemistry of Propargyldicobalt Cations: The Nicholas Reaction	W. Collins	09/28/04
Molybdenum-Catalyzed Asymmetric Allylic Alkylation	T. Bui	09/14/04
Mechanism of Grignard Reagent Formation	J. Montgomery	08/31/04
Enantioselective Free Radical Reactions	M. Ober	08/17/04
Zoanthamine Alkaloids	S. Fujimori	08/03/04
Organometallics with a Transition Metal-Bonded sp 3-Hybridized Stereogenic Carbon Atom: Development of New Tools for Asymmetric Synthesis	J. Heemstra	07/27/04
The Mechanism of Organocuprate Conjugate Additions: The Complexity of Simple Systems	S. Tymonko	07/20/04
Development of an Industrial Synthesis of Discodermolide	J. Baird	07/06/04
Synthesis, Structural Aspects and Applications of Planar Chiral (Arene)tricarbonylchromium(0) Complexes	H. Ibrahim	06/29/04
Catalytic Electronic Activation and “Borrowing” Hydrogen: New Concepts and C-C Bond Formation	M. Edwards	06/22/04
Reductive Coupling of Alkynes	C. Regens	06/01/04
Total Syntheses of Colchicine	J. Kallemeyn	05/11/04
Total Synthesis of Ciguatoxin CTX3C, a Causative Toxin of Ciguatera Seafood Poisoning	R.l Baiazitov	04/27/04
Catalytic Enantioselective a – Hydroxylation of Ketones Using Nitrosobenzene	M. Xie	04/20/04
Catalysis of 1,3-Dipolar Cycloadditions of Niitrones	M. Jo Patten	04/06/04
Atropisomer Selective Oxidative Couplings	B. Collins	03/02/04
Tosylhydrazones	C. Butler	02/24/04
Selected Synthesis of Roseophilin	T. Bui	02/09/04
Select Cascade Biomimetic Synthesis	J. Montgomery	01/27/04

Lewis Acid Catalyzed Carbonyl-Ene Reaction	M. Ober	12/16/03
Total Synthesis of Apoptolidin	W. Chung	12/09/03
Rearrangement of Allylic Imidates: Development of Asymmetric Catalysts and Application in Synthesis	S. Fujimori	11/25/03
Highlights of Schmidt Reaction in the Last Ten Years	J. Liu	11/18/03
A Little About the Chemistry of Peroxides	R. Baiazitov	11/04/03
The Total Synthesis of Tetrodotoxin	J. Heemstra	10/28/03
Selected Methods for the Creation of Asymmetric Quaternary Carbon Center	J. Baird	10/21/03
Biosynthetic Diels-Alder Reactions: Do Diels-Alderases Exist?	S. Tymonko	09/30/03
Transition Metal-Catalyzed Cycloisomerization of Terminal Alkynes	T. Bui	07/29/03
Asymmetric Hydrovinylation	J. Kallemeyn	07/15/03
Catalytic Functionalization of sp 3 C-H Bonds Adjacent to a Nitrogen Atom in Alkylamines	T. Asaumi	06/24/03
Phosphine Catalyzed Reactions	J. Montgomery	06/24/03
The Memory of Chirality, Mediated by Rotational Restriction	M. Ober	05/28/03
Bisindole Alkaloids: The Total Synthesis of (+)-Vinbiastine	R. Sweis	05/20/03
Stereoselective Ring Opening Reactions of meso-Oxabicyclic Alkenes	S. Fujimori	04/29/03
Silicon Assisted [3+2] Cycloadditions	A. Kiefer	04/22/03
Solid Phase (Asymmetric) Organic Synthesis: Novelty or Fundamental Concept?	G. Beutner	04/08/03
Catalytic Asymmetric Pauson-Khand Reaction	W.-J. Chung	02/25/03
Total Syntheses of Cylindricines, Fasicularin, and (+)-Lepadiformine	Y. Fan	02/18/03
Syntheses of Leucascandrolide A	J. Liu	02/11/03
A Novel Method of Pyrrolidine Synthesis	M. Eastgate	01/28/03
The Bounty: Total Synthesis of Callipeltoside A	J. Cottell	01/21/03
Structure, Hydroxy- and Aminoalkylation of Titanaallylsulfoximines: Enantioselective Synthesis of Unsaturated a-Amino Acids	M. Schleusner	01/14/03

Tandem Bond Forming Strategies Utilizing Brook Rearrangement	J. Heemstra	12/17/02
Selected Syntheses of Laulimalide	S. Tymonko	12/10/02
Catalytic Nucleophilic Carbenes	J. Baird	11/12/02
Aromaticity	R. Baiazitov	10/29/02
Ynolate Chemistry	J. Kallemeyn	10/22/02
Selected Total Syntheses of Gelsemine	T. Bui	10/08/02
Formyl C-H•••O Hydrogen Bonds	J. Montgomery	09/17/02
Chemical Weapons	T. Miller	08/27/02
Mechanism of the Wittig Reaction	M. Ober	08/20/02
Transannular Diels-Alder Reaction and Its Application in Total Synthesis of FR182877	S. Fujimori	08/13/02
Copper Catalyzed Allylic Oxidation Kharasch-Sosnovsky Reaction	Y. Fan	07/30/02
Diversity Oriented Synthesis	R. Sweis	07/23/02
Polypropylene Synthesis: Use of Dynamic Catalysts	G. Beutner	07/16/02
Ru Catalyzed “Atom Economical” Alkyne-Alkene Coupling Reactions	J. Fu	07/09/02
The Synthesis of ‘Warhead’ Anticancer Antibiotics	J. Cottell	06/25/02
Catalytic Asymmetric Conjugate Additions using Dialkylzinc Reagents	J. Heemstra	05/28/02
Use of Cp 2TiCl in Synthesis: Reagent Control of Radical Reactions	J. Kallemeyn	05/21/02
Asymmetric Hydride-Transfer Reduction of Ketones	R. Baiazitov	04/23/02
Synthesis of b-Lactones and b-Lactams By Catalytic Asymmetric [2+2] Cycloadditions	J. Baird	04/16/02
Novel Synthetic Transformations Mediated by IBX and DMP	T. Bui	03/26/02
Asymmetric Baeyer-Villiger Oxidations	S. Tymonko	03/19/02
Recent Advances in Enantioselective Aminocatalysis	J. Montgomery	02/19/02
Carbanionic Routes to Substituted Tolyl Sulfonamides, Acridones, and 5H-Dibenzo[b,f]azepin-10-ones	S. MacNeil	02/12/02
Zirconocene Stabilized Benzyne Complexes	M. Ober	01/29/02
Zirconocene Stabilized Benzyne Complexes [pdf] M. Ober 01/29/02 (Oxo)vanadium Catalysis	T. Miller	01/22/02
Enantio- and Regioselective Iridium-Catalyzed Allylic Substitution – Mechanism and Development	B. Bartels	01/15/02

Part 1: Regiochemistry of Aryl Radical Cyclization onto Methylenecycloalkanes and its Application to Syntheses of Calabar Alkaloids. Part 2: Convenient Synthesis of 3,3,3-Trifluoropropenyl Compounds by means of Fluoride-Mediated Horner-Wittig Reaction	T. Kobayashi	12/18/01
Catalytic Asymmetric Direct Aldol Reactions	R. Sweis	12/11/01
Lewis Acid Catalyzed Hydrometalation and Carbometalation Reactions of Unactivated Alkynes	Y. Fan	11/27/01
Bismuth Reagents in Organic Transformations	S. Fujimori	11/13/01
The Mechanism of Chorismate Mutase	G. Beutner	10/23/01
Configuration Stable Organometallic Reagents	J. Fu	09/25/01
Advances in Stereoselective Friedel-Crafts Alkylation	S. Pham	09/18/01
Synthetic Approaches Towards Azaspiracid	J. Cottell	09/11/01
Palladium Catalysis in Ionic Liquids	B. Nelson	08/28/01
Molybdenum Catalyzed Tandem Asymmetric Ring Opening Metathesis/Cross Metathesis Reactions	T. Bui	08/21/01
Highlights of the GRC Heterocyclic Compounds 2001	J. Cottell/ G. Beutner	08/21/01
Bridgehead Alkenes and the Type 2 Intramolecular Diels-Alder Reaction	J. Montgomery	08/14/01
Approaches to the Simultaneous Generation of Vicinal Quaternary Stereocenters	M. Ober	07/24/01
The Chan Reaction	T. Miller	06/26/01
1,4-Conjugate Additions Using Organoboron Compounds	S. Fujimori	06/12/01
On the Isomerization of Allylic Stannanes	T. Wynn	05/15/01
Palladium Catalyzed Asymmetric Syntheses of Chiral Allenes	Y. Fan	05/08/01
Advances in The Synthesis of Diazonamide A	R. Sweis	04/24/01
The Silylation of Nitro Compounds: Only a Set of Reactions or Synthetic Methodology to Come?	A. Tishkov	04/24/01
Transition-Metal Assisted Dearomatization of Arenes	J. Cottell	04/17/01
Mechanistic Studies of Olefin Metathesis	J. Fu	04/10/01
Metal-Fluorine Interactions in Organic Synthesis	G. Beutner	03/27/01
Rhodium Catalyzed Intramolecular Silylformylation	T. Bui	03/20/01
Total Syntheses of Asteriscanolide	S. Pham	02/27/01
Multifunctional Asymmetric Catalysis: Selected Works of Masakatsu Shibasaki	J. Montgomery	02/20/01
Catalytic Asymmetric Aziridination	M. Christy	02/13/01
Gold-Catalyzed Reactions	M. Ober	01/30/01
Ionic Liquids: Structure, Properties, & Applications	T. Miller	01/23/01
Reactions of Thiophenecarbonyls with Samarium Diiodide and their Applications	S.-M. Yang	01/16/01