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Boron-Based Crossed-Coupling Reactions

[417] Potassium Trimethylsilanolate-Promoted, Anhydrous Suzuki-Miyaura Cross-Coupling Reaction Proceeds via the “Boronate Mechanism”: Evidence for the Alternative Fork in the Trail (with C. P. Delaney, D. P. Marron, A. Shved, R. N. Zare, R. M. Waymouth) J. Am. Chem. Soc. 2022, 144, 4345-4364.

[413] Heteroaryl−Heteroaryl, Suzuki−Miyaura, Anhydrous Cross-Coupling Reactions Enabled by Trimethyl Borate (with V. Kassel, C. Hanneman, and C. Delaney) J. Am. Chem. Soc.. 2021, 143, 13845-13853.

[402] Anhydrous, Homogeneous, Suzuki-Miyaura Cross-Coupling of Boronic Esters using Potassium Trimethylsilanolate (with C. P. Delaney, E.M. Heyboer) Org. Synth., 97, 245-261.

[395] Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki–Miyaura Cross-Coupling of Boronic Esters (with Connor P. Delaney, Vincent M. Kassel) ACS Catal. 2020, 10, 73-80.

[380] Elucidating the Role of the Boronate Esters in the Suzuki−Miyaura Reaction: Structural, Kinetic, and Computational Investigations (with A. A. Thomas, A. F. Zahrt, C. P. Delaney) J. Am. Chem. Soc. 2018, 140, 4401-4416.

[369] Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction (with A. A. Thomas, H. Wang, and A. F. Zahrt) J. Am. Chem. Soc. 2017, 139, 3805-3821.

[365] Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link (with A. A. Thomas) Science. 2016, 352, 329-332.

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  • Group 16 and 17 Lewis Base Catalysis
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  • Silicon-Based Cross-Coupling Reactions
  • Water-Gas Shift Reaction
  • Phase Transfer Catalysis
  • Organoelement Chemistry
  • Allylmetal Aldehyde and Acetal Reactions
  • Aldol Chemistry
  • Nitroalkene and Related Cycloaddition (Including Tandem)
  • Chemistry of Phosphorus-Stabilized Anions
  • Dioxirane Chemistry
  • Silicon-Directed Nazarov Cyclization and Related Reactions
  • Carbanion-Accelerated Claisen Rearrangements
  • Perspectives and Reviews
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By Category

  • Group 16 and 17 Lewis Base Catalysis
  • Syn-Difunctionalization of Alkenes
  • Chemoinformatics
  • Boron-Based Cross-Coupling Reactions
  • Silicon-Based Cross-Coupling Reactions
  • Water-Gas Shift Reaction
  • Phase Transfer Catalysis
  • Organoelement Chemistry
  • Allylmetal Aldehyde and Acetal Reactions
  • Aldol Chemistry
  • Nitroalkene and Related Cycloaddition (Including Tandem)
  • Chemistry of Phosphorus-Stabilized Anions
  • Dioxirane Chemistry
  • Silicon-Directed Nazarov Cyclization and Related Reactions
  • Carbanion-Accelerated Claisen Rearrangements
  • Perspectives and Reviews
  • Miscellaneous

Department of Chemistry
University of Illinois
245 Roger Adams Lab
600 South Mathews Ave
Urbana, IL 61801
Fax: (217) 333-3984

Information for Postdoctoral Research Associate Applicants

Scott E. Denmark
Reynold C. Fuson Professor of Chemistry
sdenmark@illinois.edu
(217) 333-0066

Sarah Bransley
Coordinator of Research Programs
bransle2@illinois.edu

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