Boron-Based Crossed-Coupling Reactions

[427] Rapid, Homogenous, B-Alkyl Suzuki-Miyaura Cross-Coupling of Boronic Esters (with M. J. Bock) J. Org. Chem. 2024, XXX, XXX-XXX.
[426] Effects of Ring Size and Steric Encumbrance on Boron-to-Palladium Transmetalation from Aryboronic Esters (with C. P. Delaney, A.F. Zahrt, V.M. Kassel) J. Org. Chem. 2024, XXX, XXX-XXX.

[417] Potassium Trimethylsilanolate-Promoted, Anhydrous Suzuki-Miyaura Cross-Coupling Reaction Proceeds via the “Boronate Mechanism”: Evidence for the Alternative Fork in the Trail (with C. P. Delaney, D. P. Marron, A. Shved, R. N. Zare, R. M. Waymouth) J. Am. Chem. Soc. 2022, 144, 4345-4364.

[413] Heteroaryl−Heteroaryl, Suzuki−Miyaura, Anhydrous Cross-Coupling Reactions Enabled by Trimethyl Borate (with V. Kassel, C. Hanneman, and C. Delaney) J. Am. Chem. Soc.. 2021, 143, 13845-13853.

[402] Anhydrous, Homogeneous, Suzuki-Miyaura Cross-Coupling of Boronic Esters using Potassium Trimethylsilanolate (with C. P. Delaney, E.M. Heyboer) Org. Synth. 2020, 97, 245-261

[395] Potassium Trimethylsilanolate Enables Rapid, Homogeneous Suzuki–Miyaura Cross-Coupling of Boronic Esters (with Connor P. Delaney, Vincent M. Kassel) ACS Catal. 2020, 10, 73-80.

[380] Elucidating the Role of the Boronate Esters in the Suzuki−Miyaura Reaction: Structural, Kinetic, and Computational Investigations (with A. A. Thomas, A. F. Zahrt, C. P. Delaney) J. Am. Chem. Soc. 2018, 140, 4401-4416.

[369] Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction (with A. A. Thomas, H. Wang, and A. F. Zahrt) J. Am. Chem. Soc. 2017, 139, 3805-3821.

[365] Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link (with A. A. Thomas) Science. 2016, 352, 329-332.